Branched alkanes from blue–green algae

Squeeze-out of branched alkanes on graphite.

We study squalane and heptamethylnonane (HMN) confined between a conducting atomic force microscope tip and a graphite surface. Solvation layering occurs for both liquids but marked differences in the squeeze out mechanics are observed for ordered or disordered monolayers. The squalane monolayer at 25 degrees C is an ordered solid, as verified by direct imaging, and the squeeze out can be model...

Atom–bond connectivity and the energetic of branched alkanes

0009-2614/$ see front matter 2008 Elsevier B.V. A doi:10.1016/j.cplett.2008.08.074 * Fax: +44 01234 264722. E-mail address: [email protected] Here we introduce a new topological approach which provides a good model for the stability of linear and branched alkanes as well as the strain energy of cycloalkanes. We find that the ratio of 1,3-interactions with respect to the total number of 1,2-, ...

Sieving di-branched from mono-branched and linear alkanes using ZIF-8: experimental proof and theoretical explanation.

We study the adsorption equilibrium isotherms and differential heats of adsorption of hexane isomers on the zeolitic imidazolate framework ZIF-8. The studies are carried out at 373 K using a manometric set-up combined with a micro-calorimeter. We see that the Langmuir model describes well the isotherms for all four isomers (n-hexane, 2-methylpentane, 2,2-dimethylbutane and 2,3-dimethylbutane). ...

Generation of unusual branched long-chain alkanes from hydrous pyrolysis of anammox bacterial biomass

Adsorption and separation of linear and branched alkanes on carbon nanotube bundles from configurational-bias Monte Carlo simulation

The adsorption and separation of linear C1-nC5 and branched C5 isomers alkanes on single-walled carbon nanotube bundles at 300 K have been studied using configurational-bias Monte Carlo simulation. For pure linear alkanes, the limiting adsorption properties at zero coverage exhibit a linear relation with the alkane carbon number; the long alkane is more adsorbed at low pressures, but the revers...